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Beilstein J. Org. Chem. 2013, 9, 2216–2223, doi:10.3762/bjoc.9.260
Graphical Abstract
Scheme 1: Straightforward synthesis of organogold complexes via deprotonation reactions, using 1.
Scheme 2: Scope of the reaction between 1 and several (hetero)aromatic amines. Reaction conditions: 1 (1 equi...
Figure 1: X-ray crystal structures of complexes 2, 3, 7, 8, 10, 11 and 12. Hydrogen atoms are omitted for cla...
Figure 2: Selected examples of gold–NHC amide complexes under UV light (λ = 366 nm).
Figure 3: Excitation (blue) and emission (pink) data for complex 3, bearing a 2-pyridine ligand (see inset).
Figure 4: (a) LUMO, (b) HOMO and (c) HOMO-1 of complex 3.